A) Yes, this is the balanced equation for the reaction between Sn2+ and Tl3+.

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In summary, during the titration of 50 mL of 0.10M Sn2+ with 0.10M Tl3+, the reaction between the two results in the production of Sn4+ and Tl+. The half cell potential after adding 5.00mL of Tl3+ is approximately 0.156 volts. The formula for calculating the half cell potential is E_1_/_2=0.139-\frac{0.05196}{2}log\frac{1}{4.5}. This calculation may vary slightly depending on the logarithm ratio used.
  • #1
Mag
consider the titration of 50 mL on 0.10M Sn2+ with 0.10M Tl3+

A) Wite the equation for the reaction that occurs between Sn2+ and Tl3+

[tex]Sn^2^++Tl^3^+\longrightarrow\ Sn^4^++Tl^+[/tex]

Correct?
 
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  • #2
Thallium is most stable at 1+ oxidation state, and tin(II) ions are present to reduce it. Tin(IV) ions will be produced in this redox reaction, so your redox reaction is correct.
 
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  • #3
ok good.

what is the half cell potential after 5.00mL of Tl[tex]^3^+[/tex]?

[tex]E_1_/_2=0.139-\frac{0.05196}{2}log\frac{1}{4.5}[/tex]
[tex]E_1_/_2=0.156v[/tex]

this right also?
 
  • #4
The formula is something like that, but I don't remember the logarithm ratio in which you wrote 4.5. However, it seems okay.
 

Related to A) Yes, this is the balanced equation for the reaction between Sn2+ and Tl3+.

1. What is the balanced equation for the reaction between Sn2+ and Tl3+?

The balanced equation for the reaction between Sn2+ and Tl3+ is:
Sn2+ + Tl3+ → Sn4+ + Tl+

2. Why is this the balanced equation for the reaction?

This is the balanced equation because it follows the law of conservation of mass, which states that matter cannot be created or destroyed in a chemical reaction. This means that the number of atoms of each element must be the same on both the reactant and product side of the equation.

3. How do you determine the coefficients for the balanced equation?

Coefficients are determined by using the lowest whole-number ratio between reactants and products. This can be achieved by trial and error or by using a systematic approach such as the method of inspection or the algebraic method.

4. Can this equation be balanced using fractions as coefficients?

No, coefficients in a balanced equation must be whole numbers. Fractions are not allowed because they represent a partial amount of a substance, which goes against the law of conservation of mass.

5. What are the physical states of the reactants and products in this equation?

The physical states of the reactants and products in this equation are not specified. In order to include this information, state symbols can be added as subscripts next to each compound, such as (aq) for aqueous, (s) for solid, (l) for liquid, or (g) for gas.

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