Please help : Homework problem almost there ? Equilibrium

In summary, the conversation discusses calculating the concentrations of species at equilibrium in two scenarios: mixing water and chlorine dioxide in a 1.0L flask and placing 1.0 mol of pure hypochlorous acid in a 2.0L flask. The equation H2O + Cl2O --> 2HOCl is used to determine the equilibrium constant, Kc, which is written for concentrations. The stoichiometry is correctly represented in the exponents, and the discussion also considers the possibility of an acid-base reaction.
  • #1
marioland
2
0
linky

Kc = .090

a). Calculate the concn. of all species at equilibrium if 1.00g of water and 4.78g of ClO are mixed in a 1.0L flask.

b). Calculate the concn. of all species at equilibrium if 1.0 mol of pure HOCl is placed in a 2.0L flask. Hint: consider what is now the reactant.





H2O + Cl2O --> 2HOCl

I| 18mol 88 mol 0
C| -x -x +x
E| 18-x 88-x x

Kc= .090 = [HOCl]2 / [H2O].[Cl2O] = x2/(18-x)(88-x)


Solve for x and find all species.Is this the correct way ? Am I confusing you... *hmmm*
 
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  • #2
You're getting there, but you could use a little hint --- the equilibrium constant is written for CONCENTRATIONS --- you've got the stoichiometry in the exponents correctly --- what are the "concentrations?"
 
  • #3
You said that the reaction involved clo- and water which would be an acid base reaction.

Check to see if you wrote down the correct equation.

Acid base reaction would make more sense.
 

What is equilibrium?

Equilibrium refers to a state where the forces or factors that influence a system are balanced or equal, resulting in a stable and unchanging condition.

What is the difference between static and dynamic equilibrium?

Static equilibrium refers to a system that is at rest, while dynamic equilibrium refers to a system that is moving at a constant velocity. In both cases, the forces acting on the system are balanced, but in dynamic equilibrium, the system is still moving.

How do you calculate equilibrium?

The calculation of equilibrium depends on the specific system and the variables involved. In general, it involves setting the forces or factors that influence the system equal to each other and solving for the unknown variable.

What factors can affect equilibrium?

Factors that can affect equilibrium include changes in temperature, pressure, concentration, and the addition or removal of reactants or products. These changes can shift the balance of the system and alter the equilibrium state.

How can you manipulate equilibrium to favor a certain reaction?

Le Chatelier's principle states that a system at equilibrium will respond to any changes by shifting the equilibrium in the direction that reduces the effect of the change. This means that by manipulating the conditions of a system, such as increasing the concentration of one reactant, you can shift the equilibrium to favor a certain reaction.

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