Variational Method and Bound States

In summary: At any rate, the 1D result shows that in a sufficiently shallow potential well, there will always be a bound state. In summary, the variational method can be used to show that in the 1-dimensional case, the potential function always possesses at least one bound state, while in the 3-dimensional spherically symmetric case, it possesses no bound states if the parameter lambda squared is made sufficiently small.
  • #1
Einj
470
59

Homework Statement


Consider a potential function [itex] V(x)[/itex] such that:
$$
\begin{cases}
V(x)\leq 0\text{ for }x\in[-x_0,x_0] \\
V(x)=0 \text{ for }x\not\in[-x_0,x_0]
\end{cases}
$$
Show, using the variational method that:

(a) In the 1-dimensional case [itex]\lambda^2V(x)[/itex] always possesses at least one bound state.
(b) In the 3-dimensional spherically symmetric case, [itex]V(|\vec r|)[/itex], it possesses no bound states if [itex]\lambda^2[/itex] is made sufficiently small.



2. The attempt at a solution
The idea is to use the variational method, i.e.:
$$
\frac{\langle\psi|H|\psi\rangle}{\langle \psi|\psi\rangle}\geq E_{ground},
$$
to show that the average value of the energy is negative and hence the ground state energy is negative.

In my first attempt I used a gaussian trial function:
$$
\psi(x)=\left(\frac{2a}{\pi}\right)^{1/4}e^{-ax^2}.
$$
However the problem is that it turns out that the average value of the kinetic energy is [itex]\hbar^2a/2m[/itex] and so, in order to determine whether the average energy is negative or not we need to know [itex]a[/itex] explicitly. However, this is not possible since we have no insight on the actual shape of the potential.

It seems to me that this thing will turn out to be a problem for every trial function. How can I do that?

Thank you
 
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  • #2
In the 1D case the kinetic energy is proportional to ##a##. The potential energy is negative and goes as ##\sqrt{a}## when ##a## is small. Hence, if ##a## is small enough, the energy in that state will be negative, implying the existence of at least one bound state.

In the 3D case, the normalisation of the wave function gets additional factors of ##a## and the argument changes.
 

Related to Variational Method and Bound States

1. What is the variational method?

The variational method is a mathematical technique used to approximate the lowest energy state or ground state of a quantum mechanical system. It involves choosing a trial function, which is a mathematical expression that represents the possible wavefunction of the system, and minimizing the expectation value of the energy using calculus. The resulting energy value is an upper bound on the true ground state energy.

2. How does the variational method work?

The variational method works by finding a trial function that is as close as possible to the true wavefunction of the system. This is achieved by varying the parameters of the trial function and minimizing the expectation value of the energy. The resulting energy value is an upper bound on the ground state energy, which becomes more accurate as the trial function gets closer to the true wavefunction.

3. What is a bound state?

A bound state is a state in which a particle is confined to a finite region in space due to the presence of a potential energy barrier. In other words, the particle is unable to escape the potential well and is therefore "bound" to the system. Bound states are important in understanding the behavior of atoms, molecules, and other quantum mechanical systems.

4. How does the variational method relate to bound states?

The variational method is often used to approximate the energy levels and wavefunctions of bound states in quantum mechanical systems. By finding the trial function that minimizes the energy, the variational method can provide upper bounds on the energies of various bound states. This allows scientists to gain insight into the behavior of these systems and make predictions about their properties.

5. What are the limitations of the variational method?

The variational method is limited by the choice of trial function. If the chosen trial function is not a good representation of the true wavefunction, the resulting energy value will not be an accurate upper bound on the ground state energy. In addition, the variational method can only provide upper bounds and not exact values for the energy levels. It also becomes increasingly complex for systems with multiple particles or interactions.

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