Thermal expansion in harmonic potential

In summary, the conversation discusses the relationship between thermal expansion and the anharmonic terms in the potential of a crystalline solid. It is mentioned that in the Course of Theoretical Physics by Landau Lifshitz, a form for the coefficient of thermal expansion is derived from the free energy of a harmonic solid, which raises the question of how this is possible if a harmonic potential does not allow for thermal expansion. Ashby then suggests that the expansion coefficient is only valid for small relative displacement of atoms, within the range where the atomic bond exhibits linear elasticity.
  • #1
dam
9
0
It is generally said that thermal expansion is a process determinated by the anharmonic terms in the potential of a crystalline solid. However, in the Course of Theoretical Physics by Landau Lifshitz, Statistical Physics part 1, paragraph 67, a form for the coefficient of thermal expansion is derived from the free energy of a harmonic solid. How's that possible if in an harmonic potential no thermal expansion should be present? Thanks in advance!
 
Physics news on Phys.org
  • #2
Ashby suggests that the atomic bond exhibits linear elasticity for only small relative displacement of atoms. I presume that this is the range for which the expansion coefficient is valid.
 

Related to Thermal expansion in harmonic potential

What is thermal expansion in a harmonic potential?

Thermal expansion in a harmonic potential refers to the increase in size or volume of a material when it is heated. It occurs due to the increase in the average kinetic energy of the particles in the material, causing them to vibrate more and take up more space.

What is the relationship between temperature and thermal expansion?

The relationship between temperature and thermal expansion is directly proportional. As the temperature of a material increases, its particles gain more energy and start to vibrate more, leading to an increase in size or volume.

What is the difference between linear and volumetric thermal expansion?

Linear thermal expansion refers to the increase in length of a material when heated, while volumetric thermal expansion refers to the increase in volume. Linear expansion occurs in one direction, while volumetric expansion occurs in all directions.

What is the coefficient of thermal expansion?

The coefficient of thermal expansion is a measure of the amount of expansion a material undergoes per unit change in temperature. It is expressed in units of length per unit temperature, such as mm/m°C or in/in°F.

What factors can affect thermal expansion in a harmonic potential?

The degree of thermal expansion in a harmonic potential can be affected by various factors, such as the type of material, its composition, and the magnitude of the temperature change. The structure and arrangement of the particles in the material can also play a role in determining the extent of thermal expansion.

Similar threads

Replies
3
Views
2K
  • Quantum Interpretations and Foundations
Replies
14
Views
2K
  • Introductory Physics Homework Help
Replies
1
Views
3K
  • Advanced Physics Homework Help
Replies
2
Views
1K
  • STEM Academic Advising
Replies
6
Views
1K
  • Atomic and Condensed Matter
Replies
7
Views
4K
Replies
2
Views
1K
Replies
2
Views
3K
  • Classical Physics
Replies
0
Views
298
Back
Top