Spherical Harmonics: Why |m| ≤ l?

In summary, for physical applications of the spherical harmonics, the absolute value of m must be less than or equal to l, with both being integers. This is because m must be an integer for the exponential term to be single valued and l must also be an integer for the associated Legendre equation to be well behaved at the poles. Additionally, it can be proven from the commutation relations of the components of the angular momentum operator that m must be less than or equal to l.
  • #1
plmokn2
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Homework Statement


Why is is the for physical applications of the spherical harmonics |m| must be less than or equal to l, with both being integers?

Homework Equations


Y(m,l)=exp(im phi)P{m,l}(cos theta)
Hopefully my notation is clear, if not please say.

The Attempt at a Solution


Well m must be integer so that the the exponential is single valued as we go through 2pi on the phi axis, and l must also be integer so that the associated Legendre equation is well behaved at the poles, but I'm not sure why we require |m| is less than or equal to l? I suppose it must be something to do with the behaviour of the P part of the solution but I can't see what.

Any hints/ help appreciated,
Thanks
 
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  • #2
Well, it's possible to prove just from the commutation relations of the components of the angular momentum operator that m (the eigenvalue of Lz/hbar) must be less than or equal to l (where l(l+1) is the eigenvalue of L^2/hbar^2). Classically, Lz must be less than or equal to L^2, so this is sensible.

Edit: I meant to say that, classically, Lz^2 (not Lz) must be less than or equal to L^2.
 
Last edited:
  • #3
Thanks
 

Related to Spherical Harmonics: Why |m| ≤ l?

1. Why is |m| ≤ l in Spherical Harmonics?

The condition |m| ≤ l in Spherical Harmonics is necessary because it represents the range of values that the magnetic quantum number (m) can take. The magnetic quantum number determines the orientation of the orbital angular momentum vector in a three-dimensional space. The principal quantum number (l) represents the size and energy of the orbital, and since the orientation cannot exceed the size, |m| must be less than or equal to l.

2. What is the physical significance of |m| ≤ l in Spherical Harmonics?

The condition |m| ≤ l in Spherical Harmonics has physical significance because it represents the allowed orientations of an atomic orbital in a three-dimensional space. It determines the shape and size of the orbital, which is crucial in understanding the electronic structure and behavior of atoms and molecules.

3. Can |m| be greater than l in Spherical Harmonics?

No, |m| cannot be greater than l in Spherical Harmonics. This is because the magnetic quantum number (m) represents the number of orientations that an atomic orbital can have, and it cannot exceed the size (l) of the orbital. If |m| was greater than l, it would mean that the orbital would have orientations that are not physically possible.

4. How does the condition |m| ≤ l affect the shape of an atomic orbital?

The condition |m| ≤ l has a significant impact on the shape of an atomic orbital. For example, in the s orbital (l = 0), the magnetic quantum number (m) can only have one value (m = 0), resulting in a spherical shape. In contrast, in the p orbital (l = 1), the magnetic quantum number (m) can have three possible values (m = -1, 0, 1), resulting in a dumbbell-shaped orbital. Therefore, the condition |m| ≤ l determines the number and orientation of lobes in an atomic orbital, affecting its overall shape.

5. How is the condition |m| ≤ l related to the principle of quantum superposition?

The condition |m| ≤ l is related to the principle of quantum superposition because it allows for the combination of different atomic orbitals to form hybrid orbitals. In molecular bonding, atomic orbitals can overlap and combine, resulting in new hybrid orbitals with different shapes and orientations. The condition |m| ≤ l ensures that the orientations of the hybrid orbitals align with the allowed orientations of the atomic orbitals, in accordance with the principle of quantum superposition.

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