Solving Normalization with Psi(r)=Ne^(-ar)

In summary, the conversation is discussing the calculation of normalization for a wavefunction that depends only on the variable r. The solution involves using a triple integral in spherical coordinates and the given integral formula. The person is seeking help with understanding how to calculate the integral from 0 to infinity instead of from -infinity to +infinity with an extra factor of 4pi r^2.
  • #1
precondition
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Hi there
I'm stuck on one of the normalization question,
I'd be glad if you can help me out.
The questions is, psi(r)=Ne^(-ar) where N is a normalization constant and a is a known real parameter.
Solution reads, 1=int dr lpsi(r)l^2 = 4piN^2 int (from 0 to infinity) dr r^2 e^(-2ar)
What I don't get is how to get integral from 0 to infinity?(instead of -infinity to +infinity) with extra factor 4pi r^2?
Thanks for your help

P.S. the solution also says, use the following integral, n larger than or equal to 0: int(0 to infinity)dx x^n e^(-x)=n factorial
I don't get where you use above integral.
 
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  • #2
It seems you are stuck with math problem. Here is a little help:

In order to calculate normalization, you need to calculate volume integral from equation:

[tex]\int_{all space} |\Psi(\vec{r})|^2 d \vec{r} = 1[/tex].

Now the thing is, people use notation [tex]d\vec{r}[/tex] to actually mean a little volume element (dV if you will). In spherical coordinates, small element of space (volume) can be written as:

[tex]dV = (r \sin{\theta}) (r d\phi) dr[/tex],

where r now represents distance from the origin (the length of vector r). To cover all space when using spherical coordinates, you need to take the limits for three variables (r from 0 to infinity, theta from 0 to pi, phi from zero to 2pi; these can be easily visualized if you draw a picture). Therefore, normalization integral is actually triple integral:

[tex]\int_{r=0}^{\infty} \int_{\theta = 0}^{\pi} \int_{\phi = 0}^{2\pi} |\Psi(r, \theta, \phi)|^2 r^2 \sin{\theta} d\phi d\theta dr[/tex].

If wavefunction depends only on variable r ([tex]\Psi(\vec{r}) = \Psi(r, \theta, \phi) = \Psi(r)[/tex]), you can actually carry out integration over theta and phi. Try to do yourself from here :smile:
 
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Related to Solving Normalization with Psi(r)=Ne^(-ar)

1. How does the normalization constant N impact the wavefunction Psi(r)?

The normalization constant N determines the amplitude of the wavefunction Psi(r) and ensures that the total probability of finding the particle in any location is equal to 1. A larger value of N results in a higher amplitude and a more spread out wavefunction, while a smaller value of N results in a lower amplitude and a more concentrated wavefunction.

2. What is the relationship between the decay rate a and the width of the wavefunction Psi(r)?

The decay rate a is inversely proportional to the width of the wavefunction Psi(r). This means that a larger value of a results in a narrower wavefunction, while a smaller value of a results in a wider wavefunction. This can be seen in the exponential term, where a larger value of a leads to a faster decay of the wavefunction as r increases.

3. How does the normalization of Psi(r) affect the probability density function?

The normalization of Psi(r) ensures that the probability density function remains constant, regardless of the chosen value of N. This means that while the amplitude of Psi(r) may change, the shape and distribution of the probability density function will remain the same. This is important in accurately representing the probability of finding the particle in any location.

4. Can the normalization constant N be negative?

No, the normalization constant N must always be a positive value. This is because it represents the amplitude of the wavefunction, which cannot be negative. Additionally, a negative value for N would result in a negative probability density function, which is physically impossible.

5. Is the wavefunction Psi(r) always normalized?

No, the wavefunction Psi(r) is only normalized if the integral of its squared absolute value over all space is equal to 1. In other words, the wavefunction must satisfy the normalization condition in order to be considered normalized. If the wavefunction does not satisfy this condition, it is not normalized and must be rescaled by a constant factor in order to satisfy the condition.

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