Show that the Slater Determinant states are a complete basis

In summary, the Slater Determinant states are a set of anti-symmetric wavefunctions that form a basis in the vector space of all possible wavefunctions. This means that any wavefunction can be written as a linear combination of these states, making them a complete basis. They are a crucial tool in quantum mechanics and have many practical applications.
  • #1
kayan
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Homework Statement


"Show that the Slater Determinant states are a complete basis" is the entire statement.

Homework Equations

The Attempt at a Solution


I guess I'm trying to prove that the rank of the states is equal to the basis? I'm not sure where to start on this one.
 
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  • #2


To prove that the Slater Determinant states are a complete basis, we first need to understand what a basis is. A basis is a set of vectors that can be used to represent any other vector in a vector space. In other words, any vector in the vector space can be written as a linear combination of the basis vectors.

In quantum mechanics, the vector space is the space of all possible wavefunctions, and the basis vectors are the eigenstates of the Hamiltonian operator. The Slater Determinant states are a set of anti-symmetric wavefunctions that are constructed from single-particle wavefunctions. These single-particle wavefunctions are the basis vectors in the Slater Determinant states.

Now, to prove that the Slater Determinant states are a complete basis, we need to show that any wavefunction can be written as a linear combination of these anti-symmetric states. This can be done by using the concept of superposition. Any wavefunction can be expressed as a linear combination of basis vectors, i.e. it can be written as a sum of Slater Determinant states.

Therefore, the Slater Determinant states form a basis in the vector space of all possible wavefunctions. This means that any wavefunction can be represented as a linear combination of these states, making them a complete basis.

In conclusion, the Slater Determinant states are a complete basis because they can be used to represent any wavefunction in the vector space of all possible wavefunctions. This is why they are an important tool in quantum mechanics and are used extensively in many applications.
 

Related to Show that the Slater Determinant states are a complete basis

1. What is a Slater determinant state?

A Slater determinant state is a quantum state that describes the arrangement of electrons in a multi-electron system. It is a linear combination of single-particle states, representing all possible ways of distributing electrons among the available single-particle states.

2. What does it mean for Slater determinant states to be a complete basis?

A complete basis means that any quantum state in a multi-electron system can be expressed as a linear combination of Slater determinant states. In other words, the Slater determinant states form a basis set that spans the entire space of possible quantum states for the system.

3. How are Slater determinant states related to the Pauli exclusion principle?

The Pauli exclusion principle states that no two electrons in an atom can have the same set of quantum numbers. Slater determinant states take this into account by ensuring that no two electrons occupy the same single-particle state, thus satisfying the exclusion principle.

4. Can Slater determinant states be used for any multi-electron system?

Yes, Slater determinant states can be used for any multi-electron system, as long as the system can be described using single-particle states. This includes atoms, molecules, and solids.

5. How are Slater determinant states useful in quantum chemistry?

Slater determinant states are useful in quantum chemistry because they provide a systematic and efficient way of describing the electronic structure of multi-electron systems. They also allow for the calculation of various properties, such as energy and electronic density, which are important in understanding the behavior of these systems.

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