Kp problem with total pressure given

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In summary, for the given equilibrium at 298K with a Kp value of 0.20, a certain amount of PCl5 was added to a 1.0-L flask resulting in a total pressure of 3.00atm at equilibrium. To find the initial pressure of PCl5 in the flask, ICE tables and stoichiometry can be used to combine the known information with the unknown initial amount of PCl5. This will result in two equations with two variables, allowing for the calculation of the initial pressure of PCl5.
  • #1
marquitos
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For the equilibrium shown below, Kp = 0.20 at 298K
PCl5(g) <--> PCl (g) + Cl2 (g)
A certain amount of PCl5 is added to a 1.0-L flask. When equilibrium is reached, the total pressure in the flask is 3.00atm. What is the initial pressure of PCl5 in the flask?

If someone could point me in the right direction I'm having extreme difficulty even starting the problem, in class we haven't gone over anything like this
Thank you
 
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  • #2
Do you know how to use ICE tables?

Basically use stoichiometry of the raction to combine amounts of the substances present at equilibrium with total amount and Kp.

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  • #3
we have done ICE tables but for this reaction none of the initials are given how would I find them with the given information?
 
  • #4
You will have two variables - x (as usually in ICE tables) that refers to the amount of substances that reacted, and y - which is initial amount of PCl5. Everything else is initially at 0.

Trick is - this is not enough information to solve, but amounts of substance - when combined with known volume, temperature and pressure - will give you second equation. That means two equations in two unknowns.

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Related to Kp problem with total pressure given

1. What is the Kp problem with total pressure given?

The Kp problem with total pressure given refers to a thermodynamic issue where the equilibrium constant (Kp) calculated for a reaction does not match the experimental data when the total pressure is known. This discrepancy can occur due to various factors, such as incomplete dissociation of reactants or non-ideal behavior of gases.

2. How is the Kp problem with total pressure given solved?

The Kp problem with total pressure given can be solved by considering the effect of any non-ideal behavior of gases on the calculation of the equilibrium constant. This can be done by using more accurate equations, such as the van der Waals equation, or by including correction factors in the calculation.

3. What is the significance of the Kp problem with total pressure given?

The Kp problem with total pressure given highlights the limitations of using ideal gas behavior in thermodynamic calculations. It also emphasizes the importance of considering all factors, including non-ideal behavior, when determining the equilibrium constant for a reaction.

4. How does the Kp problem with total pressure given affect experimental results?

The Kp problem with total pressure given can lead to significant discrepancies between the calculated and experimental values of the equilibrium constant, affecting the accuracy of experimental results. This can impact the understanding of the thermodynamics of a reaction and the ability to predict and control its behavior.

5. Can the Kp problem with total pressure given be avoided?

The Kp problem with total pressure given cannot always be completely avoided, but it can be minimized by using more accurate equations and considering all factors that may affect the calculation of the equilibrium constant. Additionally, conducting experiments under conditions closer to ideal gas behavior can also help reduce the impact of this problem.

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