How could vary the Helium emission spectrum?

In summary, at high pressures, the Helium emission spectrum is modified due to interactions between the electrons of different helium atoms. This can result in both broadening and a shift in atomic spectral lines, with a greater effect on elements with vacant positions in the outer shells. For instance, at 300 K, the 1083 nm line in helium experiences a broadening of 12 MHz/Torr and a shift of -1.9 MHz/Torr, as shown in table II on page 7 of the source provided.
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In a condition of high pressure, how could vary the Helium emission spectrum?
Is this spectrum modified from the pressure?
 
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In very high pressures, the electrons will feel the electrons of other helium atoms so it will have an influence on the spectrum. I don't know exactly how such a spectrum will look, but for helium I think you needc really high pressures to give a measurable effect. I think the effect is more significant on elements with vacant positions in the outer shells since these are usually much further away from the nucleus so they are more sensitive to outside influences.
 
  • #3


There is both a broadening and a shift in atomic spectral lines as the pressure increases.

For example: for the 1083 nm line in helium, the broadening has been calculated to be 12 MHz/Torr and the shift -1.9 MHz/Torr at 300 K.

See table II on page 7 here:
http://cfa-www.harvard.edu/~hrs/PubList/PRAHe2004.pdf
 

Related to How could vary the Helium emission spectrum?

1. What is the Helium emission spectrum?

The Helium emission spectrum refers to the range of wavelengths of light emitted by Helium atoms when they are excited. This emission spectrum is unique to Helium and can be used to identify its presence in various substances.

2. How does the Helium emission spectrum vary?

The Helium emission spectrum can vary depending on the energy levels of the excited Helium atoms. The specific wavelengths of light emitted can also vary due to factors such as temperature and pressure.

3. What causes the variations in the Helium emission spectrum?

The variations in the Helium emission spectrum are caused by the different energy levels and electron transitions of the excited Helium atoms. These transitions can be affected by external factors such as temperature and pressure.

4. How can the Helium emission spectrum be used in scientific research?

The Helium emission spectrum is used in a variety of scientific research, including astronomy, chemistry, and materials science. It can be used to identify the presence of Helium in different substances and to study the energy levels and electron transitions of Helium atoms.

5. Can the Helium emission spectrum be manipulated?

Yes, the Helium emission spectrum can be manipulated by changing the conditions in which the Helium atoms are excited. By adjusting factors such as temperature and pressure, scientists can control the wavelengths of light emitted by Helium atoms and study their behavior in different environments.

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