Degenerate Perturbation Theory: Operator commuting with Ho and H'

In summary, if two degenerate states have distinct eigenvalues for a Hermitian operator A that commutes with both H0 and H', then the matrix element of the perturbation between them is zero. This can be explained by the fact that A is Hermitian and its eigenvalues are real, and the wave functions for the degenerate states are good states due to the commutation of A with H'. Therefore, the matrix element of the perturbation must be zero between these two states.
  • #1
meanyack
20
0
Homework Statement
Question is:

Prove the following:
Let A be a Hermitian operator that commutes with H0 and perturbation H'. If two degenerate states have distinct eigenvalues for A, then the matrix element of perturbation between them is zero!

The real problem is I don't understand problem completely.
I know if [A, H'] = 0, then it is called good states and one can find a unique wave functions for this. Can anyone help me about this?
 
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  • #2
Homework Equations A is a Hermitian operator, so its eigenvalues are real.[A, H0] = 0, [A, H'] = 0The Attempt at a SolutionLet A be an Hermitian operator that commutes with H0 and H'. Let λ1 and λ2 be the eigenvalues of A for two degenerate states. Since A is Hermitian, its eigenvalues are real. Now assume that λ1 ≠ λ2.We will show that the matrix element of the perturbation between the two states is zero. Since A commutes with H', it follows that [A, H'] = 0. This implies that the wave functions for the two degenerate states are good states, i.e. they are eigenstates of the combined Hamiltonian (H0 + H'). Since the wave functions are good states, the matrix element of the perturbation between them must be zero. Therefore, if two degenerate states have distinct eigenvalues for A, then the matrix element of the perturbation between them is zero.
 

Related to Degenerate Perturbation Theory: Operator commuting with Ho and H'

What is degenerate perturbation theory?

Degenerate perturbation theory is a method used in quantum mechanics to find approximate solutions for a system in which the Hamiltonian (H) operator does not commute with the perturbation operator (H'). This means that the system has degenerate energy levels, making it difficult to find exact solutions.

What does it mean for two operators to commute?

Two operators are said to commute if their order does not matter when they are applied to a system. In other words, if the operators A and B commute, then A(Bψ) = B(Aψ) for any state ψ. This is important in degenerate perturbation theory because if the Hamiltonian (H) operator commutes with the perturbation operator (H'), it makes finding exact solutions easier.

How is degenerate perturbation theory different from regular perturbation theory?

Regular perturbation theory is used when the Hamiltonian and perturbation operators do not commute, but there are no degenerate energy levels in the system. In this case, the energy levels can be easily calculated by treating the perturbation as a small correction to the Hamiltonian. Degenerate perturbation theory, on the other hand, is used when there are degenerate energy levels and requires a more complex approach to finding approximate solutions.

What is the first-order correction in degenerate perturbation theory?

The first-order correction in degenerate perturbation theory is the first term in the series expansion used to find approximate solutions. It is calculated by finding the expectation value of the perturbation operator (H') using the degenerate energy states as a basis. This correction is used to find the first approximation to the energy levels of the system.

When is degenerate perturbation theory most useful?

Degenerate perturbation theory is most useful when the system being studied has degenerate energy levels and the perturbation is small. In this case, it provides a more accurate approximation of the energy levels compared to regular perturbation theory. It is also useful when there are multiple perturbations acting on the system, as it allows for a systematic approach to finding approximate solutions.

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