Close packed structures with bases

In summary, the conversation discusses the possibility of having close-packed structures with bases, specifically focusing on the example of a face-centered cubic (FCC) structure with a two-atomic base. The participants also mention the possibility of using binary colloidal crystals as an example, where interesting structures can form depending on the ratio of the diameters of the particles.
  • #1
hokhani
483
8
Could we have close-packed structures with bases? Or, is it possible in close-packed structures that atoms of bases have arbitrary sizes? For example could we have a fcc close-packed structure with a two-atomic base (of any types of atoms)? If yes, what would happen if sizes of the bases be larger than Octahedral or tetrahedral sites' volumes?
 
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  • #2
FCC is a close-packed structure. Rock salt NaCl crystallizes in a FCC crystal structure with a 2-atom basis.

I guess, though, that the ionic radii are such that the Na ions do not "touch" each other, so the structure is not really close-packed.

A better example may be binary colloidal crystals. The colloidal particels can behave very much like hard spheres. When you mix two different sizes, interesting structures can form, depending on the ratio of the diameters.

http://www2.ph.ed.ac.uk/~abs/AB2AB13PhysRev.pdf
 
  • #3
hexagonal close packing has a two atom base.
 

Related to Close packed structures with bases

1. What are close packed structures with bases?

Close packed structures with bases refer to crystal structures that have a high packing density, where the atoms or ions are arranged in a closely packed manner with a base layer repeating in a specific pattern.

2. What are the types of close packed structures with bases?

There are three types of close packed structures with bases: hexagonal close packing (HCP), cubic close packing (CCP), and body-centered cubic (BCC). HCP has an ABABAB... stacking sequence, CCP has an ABCABC... stacking sequence, and BCC has an ABC stacking sequence.

3. How do atoms/ions arrange themselves in close packed structures with bases?

In HCP and CCP structures, the atoms/ions are arranged in a hexagonal pattern where each atom/ion has 12 nearest neighbors. In BCC structures, each atom/ion has 8 nearest neighbors arranged in a cubic pattern with an additional atom/ion at the center of the cube.

4. What are the properties of close packed structures with bases?

Close packed structures with bases have high packing densities, making them strong and stable. They also have high melting points and electrical conductivity due to the closely packed arrangement of atoms/ions.

5. What are the applications of close packed structures with bases?

Close packed structures with bases are found in many common materials such as metals, ceramics, and some polymers. They are used in various industries, including construction, electronics, and transportation, due to their strength, stability, and conductivity.

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