Calculating Wavelengths & Energy Levels of Hydrogen Atom

The higher n1 for H-alpha is 3, and for H-beta is 4. So the formula can be rewritten as 1/lambda = 1.096776 x 10^-2 ((1/2^2) - (1/3^2)) nm^-1 and 1/lambda = 1.096776 x 10^-2 ((1/2^2) - (1/4^2)) nm^-1, giving wavelengths of 656.3 nm and 486.1 nm respectively. (b) To raise an electron from the ground state to level 2, the energy required can be calculated using the formula E = -13.6/n^2 eV, where
  • #1
HjGanap
2
0

Homework Statement



the wavelengths of the emission lines produced by the hydrogen atom are given by the formula:

1/lambda = 1.096776 x 10^-2 ((1/n2^2) - (1/n1^2)) nm^-1

(a) what are the wavelengths of the first two lines in the Balmer series, H-alpha and H-beta (involving transitions to level n=2) ?

(b) calculate the energy in eV required to raise an electron from the ground state to level 2.

(c) electrons of energy 12.9 eV are fired at H atoms in a gas discharge tube. if initially all the atoms are in the ground state, what is the highest level to which the electrons in the atom can be excited? what is the longest wavelength of the possible level transitions that may then follow?

Homework Equations



as mentioned above

The Attempt at a Solution



by using data from energy-level diagram, but, confused which 1 to use for the values of n.
 
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  • #2
(a)
Since these are emission lines, the electron goes from a higher n1 to a lower n2. The lower n2, as it says, is 2.
 
  • #3


I would like to clarify that the formula provided is for the calculation of the wavelengths of the emission lines produced by the hydrogen atom, which is known as the Balmer series. The Balmer series involves transitions to level n=2, which is the second energy level of the hydrogen atom. The values of n1 and n2 in the formula represent the initial and final energy levels, respectively.

(a) For the first two lines in the Balmer series, H-alpha and H-beta, the values of n1 and n2 are 1 and 2, respectively. Plugging these values into the formula, we get the following wavelengths:

H-alpha: 656.3 nm
H-beta: 486.1 nm

(b) To calculate the energy required to raise an electron from the ground state to level 2, we can use the formula E = -13.6/n^2 eV, where n represents the energy level. Plugging in n=2, we get E = -13.6/2^2 = -3.4 eV.

(c) If electrons of energy 12.9 eV are fired at H atoms in a gas discharge tube, the highest level to which the electrons can be excited is level 3. This is because the energy of the electrons (12.9 eV) is not enough to excite them to level 4, which requires 16.2 eV. The longest possible wavelength of the level transitions that may then follow is given by the formula mentioned in the problem, with n1=3 and n2=4. Plugging these values in, we get a wavelength of approximately 1640 nm.
 

Related to Calculating Wavelengths & Energy Levels of Hydrogen Atom

1. What is the formula for calculating the wavelength of a hydrogen atom?

The formula for calculating the wavelength of a hydrogen atom is λ = hc/RH, where λ is the wavelength, h is Planck's constant, c is the speed of light, and RH is the Rydberg constant.

2. How do you calculate the energy levels of a hydrogen atom?

The energy levels of a hydrogen atom can be calculated using the formula En = -13.6/n2 eV, where En is the energy level and n is the principal quantum number.

3. What is the significance of the Rydberg constant in calculating energy levels?

The Rydberg constant is a proportionality constant that relates the energy levels of a hydrogen atom to the wavelengths of the emitted or absorbed light. It is a fundamental constant in atomic physics and is used to calculate the energy levels of other atoms as well.

4. How does the energy level of a hydrogen atom change as the principal quantum number increases?

As the principal quantum number increases, the energy level of a hydrogen atom becomes more negative. This means that the energy of the electron in the atom decreases, and it becomes more tightly bound to the nucleus. This also results in shorter wavelengths of light being emitted or absorbed by the atom.

5. Can the calculations for hydrogen atom wavelengths and energy levels be applied to other elements?

The calculations for hydrogen atom wavelengths and energy levels can be applied to other elements with only minor adjustments. The main difference is that the Rydberg constant will be different for each element, as it depends on the mass and charge of the nucleus. However, the general principles and formulas remain the same.

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